Arbejde PhD scholarship: Sulcor – Securing Corrosion Free Conditions Hovedstaden Danmarks Tekniske Universitet - jobtilbud

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stillingsbetegnelse:
PhD scholarship: Sulcor – Securing Corrosion Free Conditions

jobbeskrivelse:
Center for Energy Resources Engineering (CERE), Department of Chemical and Biochemical Engineering, Technical University of Denmark, invites applications for a 3-year Ph.D. position. The majority of goods worldwide are transported by ships. In the next 5-10 years stricter regulations on the pollution from these vessels are coming into force. These include regulations for nitrogen oxides and carbon dioxide. At the same time more stringent regulations on fuel sulfur content are introduced. A consequence is that the ship engines, for a large part designed by MAN Diesel & Turbo A/S in Copenhagen, and in particular the operation of the ship engines will be changed. One of the major challenges in this context is to prevent "cold corrosion" in the engines, which has proven to be a bigger problem when “slow-steaming” (i.e. sailing at reduced speeds). "Cold corrosion" is a mixture of acid attack and mechanical wear in the engine that occurs because the sulfuric acid to a greater extent condenses on the cylinder walls in the engines at conditions of slow-steaming where the engine runs at a reduced load. Expensive lube oil with limestone is continuously added to the cylinders to neutralize the acid generated, but the efficiency of this procedure is not always optimal. In this project, SULCOR, DTU and MAN Diesel & Turbo has teamed up with international universities in a challenging work to understand and articulate the mechanisms underlying the formation and condensation of sulfuric acid in the engines, in order to show ways to avoid the problems. Purpose of Ph.D. project The purpose of the project is to develop a mathematical model which describes surface corrosion mechanisms in the system mentioned above. This includes corrosion from e.g. SO2, SO3, H2SO4, CO2, O2 and similar gaseous components which may contribute to the overall phenomenon. Project contents The core of the project is to develop a mathematical model describing current densities on the corroding surface. It should be valid in a relative broad range from 70 to 200 °C at 50 to 200 bars. The knowledge should be constructed using literature, first principles and measurements in the lab. The conditions need to be reproduced in lab- or pilot-scale experimental set ups and the different sub -processes should be studied separately where possible. Effects of limestone and lube oil are key points to consider in the development. Relation to other Ph.D. and post doc projects The Ph.D. project is part of a larger research project, where the combined output from the different projects should lead to new engine designs and/or new operational engine procedures, which will consume less lube oil and secure low corrosion conditions. Another PhD will supply information on surface condition based on modeling and measurements. The results and ideas developed in your project will feed into a larger model describing the corrosion rate and distinguish which variables determine the corrosion. Objectives •Collect knowledge from literature study on diesel engines and the chemistry •Construct an experimental setup to measure current densities for corrosion estimation •Exchange and use of data from the other subprojects •Develop a mathematical model describing surface corrosion in diesel engines •Recommend practical use of the results Qualifications Candidates should have a master's degree in engineering or a similar degree with an academic level equivalent to the master's degree in engineering. Approval and Enrolment The scholarships for the Ph.D. degree are subject to academic approval, and the candidates will be enrolled in one of the general degree programmes of DTU. For information about the general requirements for enrolment and the general planning of the scholarship studies, please see the DTU PhD Guide. Assessment The assessment of the applicants will be made by Associate Professor Philip L. Fosbøl. Salary and appointment terms The salary a

Arbejdsgiver Navn: Danmarks Tekniske Universitet

Arbejdsgiver telefonnummer: 45252525

Arbejdsgiver faxnummer: 45881799

Job kort beskrivelse:
Undervisning og forskning på universiteter og højere læreranstalter

land: Danmark

region: Hovedstaden

krævede uddannelse: Ikke angivet

Kilde til jobtilbud: AMS, Offentlige arbejdsformidlinger, Danmark

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